The only ones I've tried that my lad hasn't managed to destroy are woof wear - he's had them nearly 6 months now and they've been excellent despite very heavy use (worn out in the field).
I never thought I'd say this, but I like the rubber pull-on ones. One of my horses is having to wear them for turnout at the moment and I have lost count of the velcro ones that she has lost or trashed. The pull on version is just so much more durable, and I like rubber as it doesn't soak up the wet like neoprene.
My Mark Todd competition over-reach boots. Neoprene with secure velcro. The medium size fits my 16hh TB perfectly, just the right length. I think they're brilliant and I wash them constantly! They've easily stood up to a year's hard work.